I recommend Tuckers Restaurant in Over-the-Rhine. They server breakfast and brunch Monday through Saturday from 9 am - 3 pm and Sundays from 10 am -2 pm. They are a true neighborhood experience and offer something for everyone. You may also want to try the Sunday brunch at Take the Cake Cafe in Northside. It is an interesting place (mainly a bakery), but they serve daily lunch and Sunday brunch. They feature a daily specials type menu, so when they run out of something it is gone.